Laboratory study demonstrates consecutive electronic excitation in boron-incorporated manganese complexes, highlighting sustainable pathways for photoredox catalysis.
Manganese complexes stand out as promising candidates for photocatalyst design, attributed to their eco- and biocompatibility, versatile valence states, and capability for facilitating multiple electronic excitations. However, several intrinsic constraints, such as inadequate visible light response and short excited-state lifetimes, hinder effective photoinduced electron transfer and impede photoredox activation of substrates. To overcome this obstacle, we have developed a class of manganese complexes featuring boron-incorporated
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Huang et al. (2024) studied this question.
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