Ultrafast polarization switching in BaTiO3 by photoactivation of its ferroelectric and central modes

We use molecular dynamics simulations with machine-learned atomistic force fields to simulate photoexcitation of BaTiO₃ by a femtosecond laser pulse whose photon energy exceeds the optical gap. We demonstrate selective displacive excitation of coherent zone-center ferroelectric mode phonons and of the strongly anharmonic central mode. We show that the direction of P can either be reversed by a pulse in hundreds of femtoseconds or, on a longer timescale and when combined with a weak field, switched to any one of its symmetry-equivalent directions.