Anionic Pt(0) and Pd(0) complexes with unprecedented trigonal bipyramidal geometry have been prepared and thoroughly characterized by experimental and computational means.Coordination of a -acceptor borane moiety supported by three phosphine buttresses enhances the electrophilicity of M(0) and triggers the binding of soft anions (X = Br, I, CN).
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Kameo et al. (2024) studied this question.
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