Studies of Galactic HII regions are of crucial importance for studying star formation and the evolution of the interstellar medium. Gaining an insight into their physical characteristics contributes to a more comprehensive understanding of these phenomena. The GLOSTAR project aims to provide a GLObal view on STAR formation in the Milky Way by performing an unbiased and sensitive survey. This is achieved by using the extremely wideband (4{-}8 GHz) C-band receiver of the Karl G. Jansky Very Large Array and the Effelsberg 100 m telescope. Using radio recombination lines observed in the GLOSTAR survey with the VLA in D-configuration with a typical line sensitivity of 1{σ} {~} 3.0 mJy beam{^-1} at {~} 5 km s{^-1} and an angular resolution of 25", we cataloged 244 individual Galactic HII regions and derived their physical properties. We examined the mid-infrared (MIR) morphology of these HII regions and find that a significant portion of them exhibit a bubble-like morphology in the GLIMPSE 8 {μ}m emission. We also searched for associations with the dust continuum and sources of methanol maser emission, other tracers of young stellar objects, and find that 48% and 14% of our HII regions, respectively, are coextensive with those. We measured the electron temperature for a large sample of HII regions within Galactocentric distances spanning from 1.6 to 13.1 kpc and derived the Galactic electron temperature gradient as {~} 372 {±} 28 K kpc{^-1} with an intercept of 4248 {±} 161 K, which is consistent with previous studies.
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