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Although various types of asymmetric cyclization reactions of 1,6-enynes have been established, simple asymmetric reductive cyclization remains underdeveloped. In this study, the enantioselective reductive cyclization of alkynyl-tethered cyclohexadienones (1,6-enynes) has been developed via a chiral pincer rhodium catalyst, affording
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Wang et al. (Tue,) studied this question.
synapsesocial.com/papers/68e61a64b6db6435875acda8 — DOI: https://doi.org/10.1021/acs.orglett.4c01276
Yi-Fan Wang
Shanghai University of Traditional Chinese Medicine
Feng Wang
Heilongjiang University of Science and Technology
Dandan Yang
Jiangxi University of Traditional Chinese Medicine
Organic Letters
Shanghai University of Traditional Chinese Medicine
Chulabhorn Research Institute
Chulabhorn Graduate Institute
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