Using new continuum and molecular line data from the ALMA Three-millimeter Observations of Massive Star-forming Regions (ATOMS) survey and archival VLA, 4.86 GHz data, we present direct observational evidence of hierarchical triggering relating three epochs of massive star formation in a ring-like H II region, G24.47+0.49. We find from radio flux analysis that it is excited by a massive star(s) of spectral type O8.5V-O8V from the first epoch of star formation. The swept-up ionized ring structure shows evidence of secondary collapse, and within this ring a burst of massive star formation is observed in different evolutionary phases, which constitutes the second epoch. ATOMS spectral line (e.g., HCO⁺(1-0)) observations reveal an outer concentric molecular gas ring expanding at a velocity of ~ 9 km\,s⁻¹, constituting the direct and unambiguous detection of an expanding molecular ring. It harbors twelve dense molecular cores with surface mass density greater than 0.05 g\,cm⁻², a threshold typical of massive star formation. Half of them are found to be subvirial, and thus in gravitational collapse, making them third epoch of potential massive star-forming sites.
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