Preparation of Antifog Hard Coatings Based on Carboxy-Functionalized Polyhedral Oligomeric Silsesquioxane Cross-Linked with Oligo(ethylene glycol)s

In this study, we prepared antifog hard coatings by heating a mixture of carboxy-functionalized polyhedral oligomeric silsesquioxane (POSS-C) and oligo(ethylene glycol)s (OEGs, HO(CH2CH2O)nH, n = 1–6) in N,N-dimethylformamide, applying the mixture onto a glass substrate, and subsequently removing the solvent via heating. In addition, we evaluated the water resistance, hardness, and antifogging performance of the coatings. In particular, the coating produced at a 2:1 functional group ratio of POSS-C to tetraethylene glycol (OEG, n = 4) coating exhibited high surface hardness (6H), as determined using pencil scratch testing. The coating remained clear after exposure to the vapor of warm water at 40 °C at a height of 2 cm for 10 s, demonstrating its antifogging property. Furthermore, no dissolution or cracking was observed when the POSS-C/OEG coating (n = 4, COOH/OH = 2:1) was immersed in water at room temperature for 1 h, confirming its water resistance. The Fourier transform infrared/attenuated total reflectance results showed the formation of ester bonds, indicating the construction of a network structure that enhanced the water resistance and hardness of the coating.