SiOC foam‐aerogel composites: Optimal balance of lightness and excellent thermal insulation

Foam‐aerogel composites are synthesized in polymeric, hybrid, and ceramic states by completing the open cells of the foam with a solution forming a wet gel, carbon dioxide (CO 2 ) supercritically dried, and pyrolyzed. Thermal diffusivity measurements are conducted using the laser flash, and for mechanical performance, cold crushing tests are done to obtain compressive strengths. Samples possess a range of specific surface area (SSA) values up to ∼650 m 2 /g contingent upon the material state, that is, polymeric, hybrid, or ceramic. While SSA values can be deliberately altered, almost all samples demonstrated a total porosity of ∼90 vol%, with superb specific compressive strength reaching around 2 MPa. In addition to adjustable surface characteristics granting hydrophobic and hydrophilic features, the study revealed the potential use of these foam‐aerogel composites as thermal insulators with low thermal conductivities of 0.02 W·m −1 ·K −1 at RT and 0.05 W·m −1 ·K −1 at 500°C. When exposed directly to a butane flame gun with a flame temperature reaching ∼1200°C, from the backside of a 5 mm‐thick foam‐aerogel composite, only ∼200°C is recorded, which is lower than a comparable commercial insulator panel tested under the same conditions.