A new polymorph of tert -butyl (2-aminophenyl)carbamate was identified using single crystal X-ray diffraction. The compound crystallised in the centrosymmetric, monoclinic space group P 2 1 / n with an asymmetric unit comprising two crystallographically-independent molecules (Zʹ = 2). This new structure was compared to that of the known polymorph with the differences between the two being attributed to a combination of space group symmetry, conformational variation, hydrogen bonding network dimensionality and crystal packing.
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Potter et al. (2024) studied this question.
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