June 8, 2024Inorganic ChemistryOpen Access

Ternary Complexes of BiI₃/CuI and SbI₃/CuI with Tetrahydrothiophene

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Synthesis yields ternary complexes combining bismuth iodide or antimony iodide with copper iodide and tetrahydrothiophene ligands, establishing distinct heterometallic frameworks.
Reactions of bismuth triiodide and antimony triiodide with copper iodide incorporate tetrahydrothiophene donors to direct crystal assembly, forming coordinated halometalate networks.
Structural characterization of these ternary complexes highlights bonding pathways between group 15 iodides and copper iodide, expanding coordination chemistry of hybrid halometalates.

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Implication

Experimental synthesis demonstrates ternary complexes of bismuth or antimony iodide with copper iodide and tetrahydrothiophene, highlighting new heterometallic coordination architectures.

Abstract

Reactions of BiI

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Ballenger et al. (2024) studied this question.

synapsesocial.com/papers/68e65981b6db6435875e7f5c https://doi.org/10.1021/acs.inorgchem.4c01147

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Implication

Experimental synthesis demonstrates ternary complexes of bismuth or antimony iodide with copper iodide and tetrahydrothiophene, highlighting new heterometallic coordination architectures.

Abstract

Reactions of BiI

Ternary Complexes of BiI₃/CuI and SbI₃/CuI with Tetrahydrothiophene

Key Points

No abstract yet

Implication

Abstract

Discussion

Cite This Study

Ternary Complexes of BiI₃/CuI and SbI₃/CuI with Tetrahydrothiophene

Key Points

No abstract yet

Implication

Abstract

Discussion

Cite This Study

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