Experimental evaluation demonstrates efficient bioavtur conversion from refined palm kernel oil over molybdenum catalysts, highlighting potential routes for sustainable aviation fuels.
done by refining the palm kernel oil with degumming method. synthesizing Mo/C catalyst by impregnating ammonium heptamolybdate tetrahydrate ((NH_4)_6Mo_7O_24·4H_2O) onto activated carbon by spray-dry impregnation, calcinating, and then reducing. The HDO reaction was done on RPKO feed with Mo/C catalysts with H_2 gas flow. The catalyst was characterized using FT-IR, XRD, SEM-EDX, nitrogen desorption with Brunnauer-Emmet-Teller (BET) and Barrett-Joyner-Teller (BJH) equation, and NH3-TPD. After HDO reaction using 3 different Mo/C catalysts, the 15-Mo/C catalyst had the highest acidity among catalysts containing Mo metal at 1.1472 mmol g^-1, catalyst area of 12.31 m^ 2 g^-1 and a pore diameter of 6.13 nm. The 15-Mo/C catalyst produced liquid product conversion of 42.52wt%, with a bioavtur yield of 41.28wt%. The 5-Mo/C and 10-Mo/C catalysts produced liquid products of 35.40 and 38.35wt% with bioavtur yields of 33.48 and 36.09wt%, respectively. The 15-Mo/C catalyst had a promising performance during the second HDO run produced a liquid product of 36.11wt% and a bioavtur yield of 34.16wt% while the third run produced a liquid product conversion of 32.84wt% with a bioavtur yield of 31.24wt%.
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Trisunaryanti et al. (2024) studied this question.
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