We argue that several potentials proposed recently for the analysis of the vibrational-rotational spectra of diatomic molecules and their thermodynamic properties exhibit a flaw. One can easily show that the parameters Dₑ and rₑ in those potentials are not the dissociation energy and equilibrium bond length, respectively, as the proposers believe. We show how to overcome the mistake in a simple and quite general way.
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Francisco M. Fernández (2024) studied this question.
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