Three-dimensional Magneto-optical Trapping of Barium Monofluoride

As a heavy molecule, barium monofluoride (BaF) presents itself as a promising candidate for measuring permanent electric dipole moment. The precision of such measurements can be significantly enhanced by utilizing a cold molecular sample. Here we report the realization of three-dimensional magneto-optical trapping (MOT) of BaF molecules. Through the repumping of all the vibrational states up to $v=3$, and rotational states up to $N=3$, we effectively close the transition to a leakage level lower than 10⁻⁵. This approach enables molecules to scatter a sufficient number of photons required for laser cooling and trapping. By employing a technique that involves chirping the slowing laser frequency, BaF molecules are decelerated to near-zero velocity, resulting in the capture of approximately 3× 10³ molecules in a dual-frequency MOT setup. Our findings represent a significant step towards the realization of ultracold BaF molecules and the conduct of precision measurements with cold molecules.