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Abstract Transition metal catalysis allows for the efficient and selective introduction of vinyl moieties onto organic molecules and offers a versatile approach to synthesizing complex organic molecules. Nonetheless, few transition ‐ metal free vinylation reactions have also been reported, exhibiting exceptional functional group tolerance and circumventing selectivity issues. This review provides an overview of carbon, nitrogen and oxygen vinylation, presenting innovative strategies and key advancements in the field. Hence, it will serve as a valuable resource for organic chemists who are interested in the synthesis of vinyl‐containing compounds. By understanding the diverse strategies involved in vinylation, readers will gain insights into harnessing this powerful synthetic methodology for the efficient construction of carbon ‐ carbon and carbon ‐ heteroatom bonds.
Papaplioura et al. (Fri,) studied this question.