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May 22, 2024Hungarian Journal of Industry and ChemistryOpen Access

Molecular Interaction Studies of Binary Mixtures of Diethyl Oxalate With Butyl Vinyl Ether, Diisopropyl Ether, Anisole and Dibutyl Ether in Terms of Thermodynamic, Transport and Acoustic Properties

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Authors

ABAjit N. BhumkarPWPralhad S. Wagh

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Overview

Experimental study reveals molecular interactions in binary diethyl oxalate and ether mixtures, highlighting thermodynamic, transport, and acoustic dependencies.

Key Points

  • Binary mixtures of diethyl oxalate with diverse ethers show distinct deviations in viscosity and excess molar volume across temperatures from 303.15 K to 313.15 K.
  • Experimental measurements of density, sound speed, and viscosity informed calculations of isentropic compressibility and free volume using Redlich-Kister polynomials.
  • Evaluations of internal pressure and viscosity models, including Grunberg-Nissan, clarify intermolecular interactions to advance liquid mixture thermodynamics.

Cite This Study

Bhumkar et al. (2024) studied this question.

synapsesocial.com/papers/68e68fc0b6db643587617730https://doi.org/10.33927/hjic-2024-04
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