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May 17, 2024Langmuir

Phenyl-Substituted Cage Silsesquioxane-Based Star-Shaped Giant Molecular Clusters: Synthesis, Properties, and Surface Segregation Behavior

Rina Tajikawa Ichiyo Tokuami Mayu Nagao Arifumi Okada Hiroaki Imoto Kensuke Naka

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Abstract

The crystallinity, solubility, and physical properties of polyhedral oligomeric silsesquioxane (POSS) compounds are highly dependent on their organic substituents. We previously synthesized a series of isobutyl-substituted star-shaped POSS derivatives with aliphatic chain linkers of different length. In this study, we prepared C3- and C6-linked phenyl-substituted star-shaped POSS derivatives (

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Cite This Study

Tajikawa et al. (2024) studied this question.

synapsesocial.com/papers/68e69859b6db64358761ed4f https://doi.org/10.1021/acs.langmuir.4c01349

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