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May 14, 2024Synfacts

Silylium Ions Catalyze the Regioselective and Diastereoselective Thiosilylation of C–C Multiple Bonds

Benjamin List Lennart J. Brücher

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Abstract

Key words difunctionalization of C–C multible bonds - thiosilylation - alkynes - allenes - silylium ions - sulfonium ions

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List et al. (2024) studied this question.

synapsesocial.com/papers/68e6a3bcb6db6435876278ba https://doi.org/10.1055/s-0043-1774838

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium InterconversionOriginal Research · 2026 · 1 citations
2Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium InterconversionOriginal Research · 2026 · 2 citations
3Thioethers as Dichotomous Electrophiles for Site‐Selective Silylation via C−S Bond CleavageOriginal Research · 2023 · 5 citations
4Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With DisulfidesOriginal Research · 2026 · 1 citations
5Iron-CatalyzedRegioselective Silylation of 1,3-Dienesto Access Multifunctional Allylic PolysilanesOriginal Research · 2026

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Nickel-catalyzed silylation of aryl thianthrenium salts with silylzinc pivalates2024
Base‐Catalyzed C( <i>sp</i> )−H Bond Silylation With Silacyclobutanes2026

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