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Abstract One of the major concerns worldwide is the rapid increase in water pollution with hazardous heavy metals. The Cucurbitnuril (CBn) structure provides an inner hydrophobic cavity accessible through two electrostatically negative portals with polar carbonyl groups, allowing for charged ion–dipole interaction between cationic species with excellent binding affinities. In this work we selected CB5, and CB7 for the titrimetric and electrochemical evaluation of the heavy metal complexes formed with Copper(II), Cadmium(II) and Lead(II). The host–guest interaction was found by either attenuation of the redox peaks, the formation of a new peak, or the slight shift in the redox peaks of the heavy metal ions. Titration data were obtained for CBn with the heavy metal solutions to determine the molar coefficient of binding. The stoichiometry of the complexes was 1 : 1 by Job′s plot. We calculated the binding constants using the Benesi–Hildebrand method achieving relatively good binding constants (K) ranging from (1.80±0.14)×10 5 –(4.98±0.13)×10 5 M −1 . The results showed that the complexes of Cadmium(II) and Lead(II) with both CB5 and CB7 are highly stable in aqueous media. Copper(II) was able to bind to the smaller sized portal of CB5, whereas with CB7 the heavy metal ion could not form a favourable complex. This phenomenon suggests that the CB5 is an ideal host at forming stable host–guest interactions than their larger homologue.
Murray et al. (Fri,) studied this question.