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October 8, 2025Angewandte Chemie International Edition

Quantifying Å‐Scale Non‐Additive Solvation at Nanoparticle Interfaces

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Authors

XLXindi LiuNCNing CaiZLZhenghan Liu

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Overview

This study demonstrates how solvent organization impacts nanoparticle behavior through SANS and Monte Carlo methods.

Key Points

  • Non-additive solvation effects were quantified, revealing complex solvent behaviors at nanoparticle surfaces.
  • Maximal solvent clustering and ligand deformation were observed at the bulk azeotropic composition.
  • Small-angle neutron scattering was used alongside Monte Carlo reconstruction to analyze interfacial solvent structures.
  • These findings highlight significant deviations from classical core-shell models for solvent effects on nanoparticles.

Cite This Study

Liu et al. (2025) studied this question.

synapsesocial.com/papers/68e6d7971ffa7aa7d63d1862https://doi.org/10.1002/anie.202516308
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