Experimental investigation demonstrates diverse fragment anion yields in ethyl acetate across 1 to 13 eV, highlighting complex nuclear rearrangements during dissociation.
The phenomenon of dissociative electron attachment to ethyl acetate is investigated within the 1 to 13 eV energy region. The recorded yields of various fragment anions within the above-mentioned energy range reveal a diverse array of products with six different mass numbers. Examples include (M-H)^-, CH₃^-, C₂H₅O^-, CH₃CO^-, CH₂CHO^-, and CH₃COO^-, formed through the fracture of single bonds. Interestingly, the generation of other fragments, such as HCCO^-, suggests a more intricate structural rearrangement of the nuclei, adding a layer of complexity to the observed dissociation dynamics.
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Paul et al. (2024) studied this question.
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