Relationship between disorder, magnetism and band topology in Mn(Sb1–xBix)₂Te₄ single crystals

We investigate the evolution of magnetic properties as well as the content and distribution of Mn for Mn(Sb 1− x Bi x ) 2 Te 4 single crystals grown by large-temperature-gradient chemical vapor transport method. It is found that the ferromagnetic MnSb 2 Te 4 changes to antiferromagnetism with Bi doping when x ≥ 0.25. Further analysis implies that the occupations of Mn ions at Sb/Bi site Mn Sb/Bi and Mn site Mn Mn have a strong influence on the magnetic ground states of these systems. With the decrease of Mn Mn and increase of Mn Sb/Bi , the system will favor the ferromagnetic ground state. In addition, the rapid decrease of T C/N with increasing Bi content when x ≤ 0.25 and the insensitivity of T N to x when x > 0.25 suggest that the main magnetic interaction may change from the Ruderman–Kittel–Kasuya–Yosida type at low Bi doping region to the van-Vleck type in high Bi doped samples.