Carbon‐Supported Ru‐Ni and Ru‐W Catalysts for the Transformation of Hydroxyacetone and Saccharides into Glycol‐Derived Primary Amines

Nitrogen-containing molecules are used for the synthesis of polymers, surfactants, agrochemicals, and dyes. In the context of green chemistry, it is important to form such compounds from bioresource. Short-chain primary amines are of interest for the polymer industry, like 2-aminopropanol, 1-aminopropan-2-ol, and 1,2-diaminopropane. These amines can be formed through the amination of oxygenated substrates, preferably in aqueous phase. This is possible with heterogeneous catalysts, however, effective systems that allow reactions under mild conditions are lacking. We report an efficient catalyst Ru-Ni/AC for the reductive amination of hydroxyacetone into 2-aminopropanol. The catalyst has been reused during 3 cycles demonstrating a good stability. As a prospective study, extension to the reactivity of (poly)carbohydrates has been realized. Despite a lesser efficiency, 2-aminopropanol (9 % yield of amines) has been formed from fructose, the first example from a carbohydrate. This was possible using a 7.5 %Ru-36 %W