A Simple Naked Eye Detection of Pb2+ on a Gold Nanocluster Decorated Disposable Paper Spot Arrays

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Among all the heavy metal ions, Lead (Pb 2+ ) has become a serious threat to human health and the environment. It is vital to develop an accurate system to monitor the Pb 2+ level. Fluorescent and colorimetric sensors are one such system to detect Pb 2+ with high accuracy. Herein, we used thiolated gold nanoclusters (GNC) decorated paper spot arrays for the detection of Pb 2+ through a simple colorimetric method. The prepared GNC and the developed complex were well-studied using various characterizations. The addition of Pb 2+ to GNC results in a slight shift in the absorption spectra from 485 nm to 534 nm. Further, GNC showed a broad emission peak centered around 650 nm, and the addition of Pb 2+ resulted in an enhancement in the peak intensity, due to cation-induced-aggregation-induced emission enhancement (AIEE). The HR-TEM analysis confirms the spherical shape of the prepared GNCs with an average size of 2.60 nm. Whereas, the addition of Pb 2+ onto GNC leads to the formation of an aggregated structure of size 6.17 nm due to the formation of a chelation complex. The GNC showed a particle size of 2 nm with a zeta potential of −16.45 mV, whereas the Pb 2+ @GNC complex exhibited an increment in an average size to 96 nm having a zeta potential of −19.67 mV, substantially demonstrating the capturing of Pb 2+ by GNC. Overall, spectroscopic and surface morphology studies indicated aggregated induced emission (AIE) phenomena between GNC and Pb 2+ . The selective detection of Pb 2+ by GNC was observed by the appearance of salmon pink to mauves colour and was captured using a smartphone. The developed paper spot array can detect up to 10 ppm of Pb 2+ . Further, the developed probe showed a distinguishable color change for Pb 2+ along with other cations of interest such as Hg 2+ , Mg 2+ , K + , Mn 2+ , and Fe 2+ . Therefore, the present paper spot array could detect Pb 2+ even in the presence of other metal ions due to its evident distinguishability. The fabricated GNC-embedded paper spot array obeys the new REASSURED criteria proposed by the World Health Organization (WHO) and could be used for on-spot detection of Pb 2+ .