Micron-Sized Cobalt Niobium Oxide with Multiscale Porous Sponge-Like Structure Boosting High-Rate and Long-Life Lithium Storage

Niobium-based oxides show great potential as intercalation-type anodes in lithium-ion batteries due to their relatively high theoretical specific capacity. Nevertheless, their electrochemical properties are unsatisfactorily restricted by the poor electronic conductivity. Here, micron-sized Co0.5Nb24.5O62 with multiscale sponge-like structure is synthesized and demonstrated to be a fast-charging anode material. It can deliver a remarkable capacity of 287 mA h g–1 with a safe average working potential of ≈1.55 V vs Li+/Li and a high initial Coulombic efficiency of 91.1% at 0.1C. Owing to the fast electronic/ionic transport derived from the multiscale porous sponge-like structure, Co0.5Nb24.5O62 exhibits a superior rate capability of 142 mA h g–1 even at 10C. In addition, its maximum volume change during the charge/discharge process is determined to be 9.18%, thus exhibiting excellent cycling stability with 75.3% capacity retention even after 3000 cycles at 10C. The LiFePO4//Co0.5Nb24.5O62 full cells also achieve good rate performance of 101 mA h g–1 at 10C, as well as an excellent cycling performance of 81% capacity retention after 1200 cycles at 5C, further proving the promising application prospect of Co0.5Nb24.5O62.