We present a study of energy density and pressure of a free real scalar quantum field after its decoupling from a thermal bath in the spatially flat Friedman-Lemaitre-Robertson-Walker space-time by solving the Klein-Gordon equation both analytically and numerically for different predetermined scale factor functions $a(t)$. The energy density and pressure, defined by subtracting the vacuum expectation values at the decoupling time, feature corrections with respect to the classical free-streaming solution of the relativistic Boltzmann equation. We show that if the expansion rate is comparable or larger than mc²/ or KT₀/ where m is the mass and T₀ the decoupling temperature, both energy density and pressure gets strong quantum corrections which substantially modify their classical dependence on the scale factor $a(t)$ and drive pressure to large negative values. For a minimally coupled field with a very low mass in an expanding de Sitter universe quantum corrections are dominant driving pressure and energy density to become asymptotically constant with an equation of state p/ε -1, thereby mimicking a cosmological constant. For a minimally coupled massless field, quantum corrections are asymptotically dominant for any accelerated expansion.
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Becattini et al. (2024) studied this question.
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