Palladium Catalysis: Dependence of the Efficiency of C–N Bond Formation on Carboxylate Ligand and Metal Carboxylate or Carboxylic Acid Additive

The Pd-catalyzed inter- and intramolecular reactions of nitrogen compounds are often carried out with palladium carboxylates, sometimes in the presence of carboxylic acids or alkali metal carboxylates. This Mini-Review highlights the dependence of the reaction efficiency on the nature of the ligand and the carboxylate additives. The proposed reaction mechanisms are presented with, as far as possible, personal comments.