Crystallographic Disorder and Strong Magnetic Anisotropy in Dy₃Pt₂Sb4.48

We report the crystal growth and characterization of a rare-earth-containing material, Dy3.00(1)Pt2Sb4.48(2). This compound possesses a similar structure to the previously reported Y3Pt4Ge6, but it lacks two layers of Pt atoms. Crystallographic disorder was found in Dy3.00(1)Pt2Sb4.48(2). Additionally, the Dy–Dy framework was found to have both square net and triangular lattices. Dy3.00(1)Pt2Sb4.48(2)8 was determined to be antiferromagnetically ordered around ∼15 K while a competing antiferromagnetic sublattice also exists at lower temperature. Strong magnetic anisotropy was observed, and several metamagnetic transitions were seen in the hysteresis loops. Furthermore, the Curie–Weiss fitting revealed an unusually small effective moment of Dy, which is far below the expected value of Dy3+ (10.65 μB). This material might provide a new platform to study the relationship between crystallographic disorder and magnetism.