Improved power conversion efficiency and stability of perovskite solar cells induced by dual interface passivation

Efficient and stable Perovskite solar cells (PSCs) have been successfully produced using a dual-layer modified (DLM) perovskite thin film. This method simultaneously modifies both the bottom (SnO₂/perovskite) and top (perovskite/Spiro- OMeTAD) interfaces of the perovskite. The crystallinity of the perovskite film is enhanced after the DLM treatment. Additionally, thin barrier layers are formed on both its bottom and top surfaces, which reduce surface defect density and non-radiative recombination of carriers. The bottom and top modifier layers prevent direct contact between the hole transport layer and the electron transport layer, forming a high-energy barrier that promotes carrier transmission in PSCs. Consequently, the methylammonium acetate (MAAc)-PSC achieves an efficiency of 21.96%.