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This is a Experimental Study study.

October 10, 2025Open Access

Time resolved determination of anomeric rates of glucose-6-phosphate: success and limitations of dissolution-DNP

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Analysis reveals kinetic details of glucose-6-phosphate anomerization using hyperpolarized NMR, suggesting new insights into molecular dynamics.

Rate parameters of glucose-6-phosphate anomerization were successfully measured using hyperpolarized NMR.
The study demonstrated the effectiveness of dynamic dissolution nuclear polarization in quantifying subtle dynamic equilibria.
Kinetic models were tested to analyze the anomerization process in various experimental conditions.
Findings highlight the limitations and success of hyperpolarized techniques for observing fast chemical processes.

Soussi-Thérond et al. (2025) studied this question.

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Analysis reveals kinetic details of glucose-6-phosphate anomerization using hyperpolarized NMR, suggesting new insights into molecular dynamics.