Hypervalence and octet-expansion in trimethylene-λ6-sulfane and related species.

Henry S. Rzepa

doi:10.59350/zae7v-e2w70

November 27, 2017Open Access

Hypervalence and octet-expansion in trimethylene-λ6-sulfane and related species.

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Key Points

Hypervalence impacts single bond properties in trimethylene-λ6-sulfane and related species, unveiling complex structures.
ELF basins indicate intriguing internal structures within the single bonds of compounds like SeMe6 and SMe6.
Non-polar species exemplify the unique characteristics of single bonds, highlighting their structural importance.
The exploration of electron localization function (ELF) provides a deeper understanding of bond behaviors in these compounds.

Implication

This analysis reveals octet-expansion in hypervalent compounds, indicating new insights into single bond structure.

Abstract

Previously: "Non-polar" species such as SeMe ₆ , SMe ₆ , ClMe ₃ , ClMe ₅ all revealed interesting properties for the Se-C, S-C or Cl-C "single" bonds. The latter two examples in particular hinted at internal structures for these single bonds, as manifested by two ELF basins for some of the bonds.

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Cite This Study

Henry S. Rzepa (2017) studied this question.

synapsesocial.com/papers/68e865117ef2f04ca37e510f https://doi.org/10.59350/zae7v-e2w70

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Hypervalence and octet-expansion in trimethylene-λ6-sulfane and related species.

Key Points

Implication

Abstract

Discussion

Cite This Study

Hypervalence and octet-expansion in trimethylene-λ6-sulfane and related species.

Key Points

Implication

Abstract

Discussion

Cite This Study

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