Octet expansion and hypervalence in dimethylidyne-λ6-sulfane.

Henry S. Rzepa

doi:10.59350/h253h-5tx96

November 28, 2017Open Access

Octet expansion and hypervalence in dimethylidyne-λ6-sulfane.

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Key Points

Dimethylidyne-λ6-sulfane exhibits notable octet expansion phenomena, highlighting unique bonding traits.
The study identifies hypervalence in the context of hypercoordinate sulfur species, expanding known chemistry.
Research transitions from S(-CH3)6 to S(=CH2)3, culminating in an analysis of S(≡CH)2 cases.
Understanding these structures could provide insights into chemical behavior and reactivity in similar compounds.

Implication

Analysis reveals octet expansion and hypervalence characteristics in non-polar hypercoordinate species, focusing on sulfane.

Abstract

I started this story by looking at octet expansion and hypervalence in non-polar hypercoordinate species such as S(-CH3)6, then moved on to S(=CH2)3. Finally now its the turn of S(≡CH)2.‡

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Cite This Study

Henry S. Rzepa (2017) studied this question.

synapsesocial.com/papers/68e865117ef2f04ca37e510e https://doi.org/10.59350/h253h-5tx96

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Octet expansion and hypervalence in dimethylidyne-λ6-sulfane.

Key Points

Implication

Abstract

Discussion

Cite This Study

Octet expansion and hypervalence in dimethylidyne-λ6-sulfane.

Key Points

Implication

Abstract

Discussion

Cite This Study

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