Bimetallic aluminum complexes bearing β-pyridyl-enamino ligands: synthesis, characterization and their applications in the ring-opening polymerization of ε-caprolactone

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This is a Experimental Study study.

Peng Wang; ZH Su; Zhuo Yang; Jianhua Cheng; Hengquan Yang; Israel M. Kibeye; Xia Chen

doi:10.1039/d5py00481k

January 1, 2025Polymer Chemistry

Bimetallic aluminum complexes bearing β-pyridyl-enamino ligands: synthesis, characterization and their applications in the ring-opening polymerization of ε-caprolactone

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Key Points

Bimetallic aluminum complexes exhibit high yields in synthesis, enhancing their potential in applications.
Single-crystal X-ray diffraction confirmed the structures of several synthesized complexes, indicating successful characterization.
Ring-opening polymerization of ε-caprolactone was successfully facilitated by the newly synthesized ligands, demonstrating their efficacy.
The study suggests that these complexes could lead to advancements in polymer synthesis techniques, with applications in various fields.

Implication

Synthesis and characterization of bimetallic aluminum complexes highlight their role in ε-caprolactone polymerization.

Abstract

A series of bridged β-pyridyl-enamino dinuclear aluminum complexes 1–6 have been prepared in high yields, where complexes 1, 2, 3, 5 and 6 were characterized by single-crystal X-ray diffraction. The...

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Cite This Study

Wang et al. (2025) studied this question.

synapsesocial.com/papers/68e9b1c1ba7d64b6fc13245c https://doi.org/10.1039/d5py00481k

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Bimetallic aluminum complexes bearing β-pyridyl-enamino ligands: synthesis, characterization and their applications in the ring-opening polymerization of ε-caprolactone

Key Points

Implication

Abstract

Discussion

Cite This Study

Bimetallic aluminum complexes bearing β-pyridyl-enamino ligands: synthesis, characterization and their applications in the ring-opening polymerization of ε-caprolactone

Key Points

Implication

Abstract

Discussion

Cite This Study

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