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October 14, 2025Inorganic Chemistry

Synthesis and Reactivity of an Iminoborane-Boraalkene Adduct via the Complete Cleavage of the Carbon–Nitrogen Triple Bond of Isonitrile

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Authors

YZY. ZhangJLJiazhong LiHWHao Wang

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Overview

The research demonstrates iminoborane-boraalkene adduct synthesis in isonitrile reactions, indicating novel reactivity pathways.

Key Points

  • The complete cleavage of the C≡N triple bond in isonitrile was key to forming the iminoborane-boraalkene adduct.
  • Density functional theory calculations provided insights into the reaction mechanisms involved in adduct formation.
  • The iminoborane-boraalkene complex exhibited unique reactivity patterns, including interactions with phenyllithium and THF.
  • This work introduces a new class of boron-containing compounds via the transformation of an isonitrile substrate.

Cite This Study

Zhang et al. (2025) studied this question.

synapsesocial.com/papers/68ee65af92c779260ada216ahttps://doi.org/10.1021/acs.inorgchem.5c04211
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