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October 15, 2025Journal of the American Chemical Society

Carbene Zipper Reaction for Cascade π-Extension

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Authors

HLHongxu LvLBLeiyang BaiXJXuefeng Jiang

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Overview

This research demonstrates cascade π-extension in polycyclic aromatic hydrocarbons, indicating precise control of structures.

Key Points

  • Cascade π-extension allows precise synthesis of polycyclic aromatic hydrocarbons, enhancing nanographenes' properties.
  • The method demonstrates tunable lengths and structural control, crucial for exploring graphene-based materials.
  • Copper-catalyzed domino carbene transfer is instrumental in achieving versatile twisted π-systems with aromaticity variations.
  • The findings highlight the relationship between structure and properties in nanographenes, indicating potential applications.

Cite This Study

Lv et al. (2025) studied this question.

synapsesocial.com/papers/68eff7392ae617e5891a9448https://doi.org/10.1021/jacs.5c14209
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