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October 17, 2025Chemistry - An Asian Journal

Plasmon‐Driven C─B Bond Cleavage: Role of Metal Nanobipyramids' Sharpness

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Authors

CKCharanleen KaurSRShikha RaiPSPriyanka Singhmar

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Overview

This study shows superior photocatalytic performance of gold nanobipyramids in bond cleavage, indicating structural influence.

Key Points

  • Au NBPs demonstrated a 65% yield in bond cleavage reactions within 5 minutes under laser irradiation.
  • Ag-coated NBPs showed lower yields (44%-55%) and longer reaction times, despite enhanced SERS signals.
  • Mechanistic studies indicate that hot charge carriers are responsible for bond cleavage rather than photothermal effects.
  • Insights gained from structure-activity relationships highlight the potential of Au NBPs in plasmon-enhanced catalytic applications.

Cite This Study

Kaur et al. (2025) studied this question.

synapsesocial.com/papers/68f199c5de32064e504dd08ehttps://doi.org/10.1002/asia.70381
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