Self-doped and planar nitrogen-bay-functionalized perylene diimides: unravelling structure-property relationships

Kathryn M. Wolfe; Zachary Gardner; Zachary K Smith; Alexander Harrison; Chad Risko; Gregory C. Welch

doi:10.1039/d5sc06640a

January 1, 2025Chemical ScienceOpen Access

Self-doped and planar nitrogen-bay-functionalized perylene diimides: unravelling structure-property relationships

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Key Points

Modulating electronic properties can enhance the usability of organic semiconductors.
Core twisting in perylene diimides reduces π-conjugation, compromising performance.
The study emphasizes the importance of planarity in determining electronic characteristics.
Understanding structure-property relationships can lead to better semiconductor designs.

Implication

This analysis reveals how core twisting affects electronic properties in perylene diimides, suggesting ways to improve their performance.

Abstract

Bay-functionalized perylene diimides (PDIs) offer a strategy for modulating electronic properties in organic semiconductors but can suffer from core twisting and reduced planarity, leading to compromised π-conjugation and disruption of...

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Cite This Study

Wolfe et al. (2025) studied this question.

synapsesocial.com/papers/68f396388da44caaba02c993 https://doi.org/10.1039/d5sc06640a

View Full Paper

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Self-doped and planar nitrogen-bay-functionalized perylene diimides: unravelling structure-property relationships

Key Points

Implication

Abstract

Discussion

Cite This Study

Self-doped and planar nitrogen-bay-functionalized perylene diimides: unravelling structure-property relationships

Key Points

Implication

Abstract

Discussion

Cite This Study

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