Palladium-catalysed asymmetric annulations of Morita-Baylis-Hillman carbonates with allenes or alkenes via migratory insertion

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This is a Experimental Study study.

Jinyu Huang; Xiang Qin; Han-Wen Rao; Zhichao Chen; Lei Zhu; Qin Ouyang; Wei Du; Ying‐Chun Chen

doi:10.1039/d5sc06910f

January 1, 2025Chemical ScienceOpen Access

Palladium-catalysed asymmetric annulations of Morita-Baylis-Hillman carbonates with allenes or alkenes via migratory insertion

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Key Points

The study shows that palladium-catalyzed asymmetric annulations can effectively utilize Morita-Baylis-Hillman carbonates with good yields.
Key findings reveal that the migratory insertion mechanism significantly influences the reaction outcomes, enhancing selectivity.
This work employs a novel palladium catalyst approach to connect carbonates with diverse nucleophiles, informing future synthetic methodologies.
The implications of these reactions point to broader applications in organic synthesis, enabling varied functional group transformations.

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Implication

This research reveals the potential of palladium in asymmetric annulations using Morita-Baylis-Hillman carbonates, suggesting novel pathways for synthetic applications.

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Cite This Study

Huang et al. (2025) studied this question.

synapsesocial.com/papers/68f408995de60f8893c7007c https://doi.org/10.1039/d5sc06910f

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Palladium-catalysed asymmetric annulations of Morita-Baylis-Hillman carbonates with allenes or alkenes via migratory insertion

Key Points

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Implication

Abstract

Discussion

Cite This Study

Palladium-catalysed asymmetric annulations of Morita-Baylis-Hillman carbonates with allenes or alkenes via migratory insertion

Key Points

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Implication

Abstract

Discussion

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