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This analysis reveals time advance and probability conservation in quantum mechanics, suggesting unique excitation and decay mechanisms.
When excited states decay the time evolution operator U(t)=e-iHt does not obey U^(t)U(t)=I. Nonetheless, probability conservation is not lost if one includes both excitation and decay, though it takes a different form. Specifically, if the eigenspectrum of a Hamiltonian is complete, then due to $CPT$ symmetry, a symmetry that holds for all physical systems, there must exist an operator V that effects VHV⁻¹=H^, so that V⁻¹U^(t)VU(t)=I. In consequence, the time delay associated with decay must be accompanied by an equal and opposite time advance for excitation. Thus when a photon excites an atom the spontaneous emission of a photon from the excited state must occur without any decay time delay at all. An effect of this form together with an associated negative time delay appear to have recently been reported by Sinclair et. al., PRX Quantum 3, 010314 (2022) and Angulo et. al., arXiv:2409.03680 [quant-ph].
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Philip D. Mannheim (2025) studied this question.
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