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New organophotocatalyzed protocol introduces trifluoroethyl and ester groups in alkenes, suggesting a radical mechanism.
A metal‐free, organophotocatalyzed three‐component reaction between alkenes, 2,2,2‐trifluoroiodoethane, and carboxylic acids was developed. This protocol simultaneously introduces a trifluoroethyl group and an ester moiety in a single step. Preliminary mechanistic studies suggest the reaction proceeds via a radical pathway.
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Zeng et al. (2025) studied this question.
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