Tidal fluctuations and spatial heterogeneity lead to trapping and chaotic mixing in coastal aquifers

The combined effect of tidal forcing and aquifer heterogeneity leads to intricate transport patterns in coastal aquifers that impact both on solute residence times and mixing dynamics. We study these patterns through detailed numerical simulations of density-dependent flow and transport in a three-dimensional heterogeneous coastal aquifer under tidal forcing. Advective particle tracking from both the freshwater and seawater domains reveals the formation of chaotic and periodic orbits in the freshwater-saltwater transition zone that may persistently trap contaminants. We find that increasing heterogeneity results in increased trapping, but also increased mixing entropy, which suggests that the chaotic orbits enhance mixing between contaminants from the freshwater and seawater domains. These findings highlight on the one hand, the long-term contamination risks of coastal aquifers through trapping, and on the other hand, the creation of hotspots for chemical and biological reactions through chaotic mixing in the transition zone.