Organo-Photocatalyzed Deoxygenative Alkylcarboxylation of Olefins with Alcohols and CO2

Q: What type of study is this?

This is a Experimental Study study.

Zeyou Wang; Yilin Ding; Yaxin Lou; Jin Kun; Jihong Liu; Xiujuan Feng; Ming Bao; Xuan Zhang

doi:10.1039/d5gc04497a

January 1, 2025Green Chemistry

Organo-Photocatalyzed Deoxygenative Alkylcarboxylation of Olefins with Alcohols and CO2

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Key Points

The method demonstrates effective alkylative carboxylation of olefins under photocatalysis using CO2.
Yield of alkyl radicals was successfully achieved from alcohols through a desulfurative mechanism.
The approach involves photocatalytic activation, integrating CO2 to drive the alkylation process with high efficiency.
Potential applications include the utilization of renewable resources in carbon capture and conversion strategies.

Implication

This protocol reveals photocatalytic carboxylation of alkenes using alcohols and CO2, suggesting new alkylation methods.

Abstract

Herein we report a general protocol of CO2 participated alkylative carboxylation of alkenes under photocatalysis, where alcohols serve as alkyl sources to provide alkyl radicals via a desulfurative process from...

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Cite This Study

Wang et al. (2025) studied this question.

synapsesocial.com/papers/68f83319d24b29c969481a7a https://doi.org/10.1039/d5gc04497a

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Organo-Photocatalyzed Deoxygenative Alkylcarboxylation of Olefins with Alcohols and CO2

Key Points

Implication

Abstract

Discussion

Cite This Study

Organo-Photocatalyzed Deoxygenative Alkylcarboxylation of Olefins with Alcohols and CO2

Key Points

Implication

Abstract

Discussion

Cite This Study

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