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October 23, 2025Journal of Porphyrins and Phthalocyanines

Syntheses, structures and properties of a phthalocyanine peripherally introduced with bis(3,5-trifluoromethyl)phenyl substituents and its zinc(II) and cobalt(II) complexes

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Authors

MHMakoto HandaTYTomonori YomotoNYNatsumi Yano

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Overview

Synthesis of phthalocyanine complexes with zinc(II) and cobalt(II) shows distinct electrochemical oxidation behavior.

Key Points

  • The phthalocyanine complexes displayed distinct oxidation waves at various potentials, indicating differing redox properties.
  • The zinc(II) complex exhibited a half-oxidation potential of 0.43 V, while the cobalt(II) complex had a higher potential of 0.91 V.
  • Characterization included techniques like X-ray crystallography and MALDI-TOF mass spectrometry, confirming structural integrity.
  • Findings suggest potential applications in electronic and optoelectronic devices, highlighting phthalocyanine's unique properties.

Cite This Study

Handa et al. (2025) studied this question.

synapsesocial.com/papers/68fa1210f9f8b44535bfce18https://doi.org/10.1142/s1088424625501032
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