Interplay of distinct modes of charge regulation on poly-acid ionization and conformation

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Discussion

Theoretical analysis reveals ionization and charge behavior changes in polymeric systems, suggesting counterion effects.

Ionization patterns change significantly with different pH levels, revealing complex polymeric interactions with solvent.
Counterion condensation influences polyelectrolyte behaviors, demonstrating both anti- and conventional properties under varying salt levels.
Theoretical framework adaptation allows for insights into proton binding and charge dynamics in polymeric chains.
Findings indicate substantial pKa shifts in semi-flexible chains compared to traditional monoacids, highlighting unique characteristics.

Ghosh et al. (2025) studied this question.

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