Macrocycle‐Conjugated Anthracenes Enable Thermochromic, Mechanochromic, and Supramolecular Polymorphic Properties in Organic Crystals

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Thermochromic behaviors enhanced through distinct aggregation patterns in organic crystals—specifically, the flexibility of An-LP6.
Supramolecular interactions manipulate properties, allowing modular control of intermolecular interactions and their effects on light behavior.
Assessment using density functional theory and X-ray crystallographic analyses underpins findings about the structure-function relationship in crystals.
Significance lies in the potential for adaptive organic materials that leverage supramolecular polymorphism for innovative applications.

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Investigation reveals conjugated anthracenes enable supramolecular polymorphism in organic crystals, suggesting new optoelectronic applications.

Song et al. (2025) studied this question.

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Investigation reveals conjugated anthracenes enable supramolecular polymorphism in organic crystals, suggesting new optoelectronic applications.