Mononuclear Fe II and Heterobinuclear Fe II Ni II Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties

Vanessa Stephan; Christian Zocher; Martin Börner; Jennifer Klose; Daniel Fuhrmann; Berthold Kersting

doi:10.1039/d5dt02350e

January 1, 2025Dalton TransactionsOpen Access

Mononuclear Fe II and Heterobinuclear Fe II Ni II Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties

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Key Points

Properties of the synthesized FeNi thiolate complex were characterized to reveal its structural attributes and implications for transition metal chemistry.
The mixed-ligand FeNi thiolate complex was obtained, leading to insights about the performance of macrocycles in metal coordination.
Analysis involved the utilization of hexaazadithiophenolato ligand to create heterobinuclear complexes with unique properties.
The findings highlight the significance of macrocycles in synthesizing diverse transition metal complexes for potential applications.

Implication

Synthesis of a FeNi thiolate complex reveals key properties of macrocycles in transition metal complexes, suggesting novel applications.

Abstract

Compartmental macrocycles have proven to be very successful for the synthesis of heterobinuclear transition metal complexes. We obtained a mixed-ligand FeNi thiolate complex, [FeNiL(µ-OAc)]ClO 4 ( 3 ), where L 2- represents a 24-membered...

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Stephan et al. (2025) studied this question.

synapsesocial.com/papers/692502ad87af00ed34ac1c03 https://doi.org/10.1039/d5dt02350e

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Mononuclear Fe II and Heterobinuclear Fe II Ni II Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties

Key Points

Implication

Abstract

Discussion

Cite This Study

Mononuclear Fe II and Heterobinuclear Fe II Ni II Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties

Key Points

Implication

Abstract

Discussion

Cite This Study

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