November 10, 2025Inorganic ChemistryOpen Access

Pentagonal Bipyramidal First-Row Transition Metal Complexes with Macrocyclic Ligand Containing Two Pyridine- N -Oxide Pendant Arms: Structural, Magnetic, and Theoretical Studies

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Structural analysis reveals magnetic anisotropy in first-row transition metal complexes, implying diverse applications in molecular magnets.

Magnetic anisotropy was pronounced in transition metal complexes with coordination numbers of 7 or 5 + 2.
Theoretical calculations supported experimental data, particularly for magnetic anisotropy metrics of the complexes.
X-ray crystal structure analyses confirmed the pentagonal bipyramidal geometry across multiple metal complexes.
Magneto-structural correlations highlighted the importance of functional groups in achieving optimal magnetic performance.

Drahoš et al. (2025) studied this question.

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Structural analysis reveals magnetic anisotropy in first-row transition metal complexes, implying diverse applications in molecular magnets.