Domino reaction improved the synthesis of one-pot 1,4-phosphonyl fullerenols, suggesting potential fullerene complexes.
A DBU-promoted, multicomponent domino reaction involving H-phosphonates, C₆₀, and HBr/DMSO has been developed for the efficient one-pot synthesis of 1,4-(phosphonyl)[60]fullerenols. Investigations into the coordination reactions of these 1,4-phosphorylated fullerenols with Pt(PPh₃)₄ have facilitated the synthesis of two distinct types of 1,4-diorgano[60]fullerene platinum complexes. Furthermore, control experiments revealed the unique reactivity of 1,2-(phosphonyl)(hydro)[60]fullerene with HBr/DMSO.
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Li et al. (2025) studied this question.
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