Analysis reveals cationic structures in Cu complex enhancing catalysis for peroxidative alkane functionalizations.
The first metallacomplex, containing simultaneously 1,3-bis(diphenylphosphino)propane and silsesquoxane ligands, adopts intriguing three-component ionic structure. According to X-ray diffraction studies, central dianionic CuII12-methylsilsesquioxane cage is balanced by two external cationic [CuI(dppp)2]...
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Arteev et al. (2025) studied this question.
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