Rheology of bidisperse suspensions at the colloidal-to-granular transition

We use particle-based simulation to study the rheology of dense suspensions comprising mixtures of small colloids and larger grains subject to contact, lubrication and Brownian forces. These suspensions exhibit shear thinning at low shear rates and shear thickening at high shear rates. By systematically varying the volume fraction of the two species, we demonstrate a monotonic increase in viscosity when grains are added to colloids, but, conversely, a non-monotonic response in both the viscosity and shear-thickening onset when colloids are added to grains. Both effects are most prominent at intermediate shear rates where diffusion and convection play similar roles in the dynamics. We rationalise these results by measuring the maximum flowable volume fraction as functions of the Péclet number and composition, showing that in extreme cases increasing the solids content can disrupt grain contacts and thus allow a jammed suspension to flow. These results establish a constitutive description for the rheology of bidisperse suspensions across the colloidal-to-granular transition, with implications for flow prediction and control in multicomponent particulate systems.