Analysis shows lithium perchlorate solutions exhibit unique conductivity and stability in sulfolane-alkyl acetate mixtures, indicating complex interactions.
The physicochemical properties of 1.0 M solutions of lithium perchlorate in mixtures of sulfolane with methyl-, ethyl-, and butyl acetate have been studied and it has been found that the introduction of alkyl acetates leads to a decrease in the toughness of electrolyte solutions and an expansion of the temperature range of the liquid-phase state. The isotherms (30°C) of the specific ion conductivity of 1.0 M solutions of lithium perchlorate in sulfolane-alkyl acetate mixtures show maxima, the position of which is determined by the molecular weight of alkyl acetate. The electrochemical stability window of 1.0 M solutions of LiClO in sulfolane-alkyl acetate mixtures is 5.7–5.8 V vs. Li/Li.
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L. V. Sheina (2025) studied this question.
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